Visible Light Photocatalyzed Redox-Neutral Organic Reactions and Synthesis of Novel Metal-Organic Frameworks by Basudev Sahoo

Title: Visible Light Photocatalyzed Redox-Neutral Organic Reactions and Synthesis of Novel Metal-Organic Frameworks
Editor: Basudev Sahoo
Edition: Illustrated
Publisher: Springer Publications
Length: 274 pages
Size: 11.5 MB
Language: English

Book Description:

This unique thesis discusses the development of conceptually novel and synthetically valuable methods that use visible light photocatalysis. Each chapter addresses a different topic in the emerging field of photocatalysis, which has become an indispensable tool for organic synthesis. Photocatalysis employs environmentally harmless and abundant visible light in the presence of a photosensitizer, and as such offers an attractive alternative to harmful UV light in photo-mediated reactions. This book introduces the novel concept of merging gold catalysis with visible light photocatalysis in a dual catalytic fashion, which demonstrates their compatibility with each other for first time and has inspired the development of various reactions. Moreover, a novel trifluoromethylation method, which combines radical addition chemistry with a polar rearrangement to synthesize valuable fluorinated compounds, is presented, since compounds featuring fluorinated functionality are the subject of increasing attention in pharmaceutical, agrochemical and material research. It also develops an external photocatalyst-free photochemical method for the synthesis of valuable indolizine heterocycles, where the product mediates its own formation. Lastly, it describes the synthesis and characterization of two novel highly porous metal-organic frameworks (MOFs). The comprehensive text is rounded out with illustrations and color figures.

Visible Light Photocatalyzed Redox-Neutral Organic Reactions and Synthesis of Novel Metal-Organic Frameworks

Author(s): Basudev Sahoo (auth.)

Series: Springer Theses

Publisher: Springer International Publishing, Year: 2017

ISBN: 978-3-319-48349-8

 

[PDF] Visible Light Photocatalyzed Redox-Neutral Organic Reactions and Synthesis of Novel Metal-Organic Frameworks by Basudev Sahoo Table Of Contents

Front Matter….Pages i-xxiii
Introduction to Photocatalysis….Pages 1-23
Dual Gold and Visible Light Photoredox-Catalyzed Heteroarylations of Non-activated Alkenes….Pages 25-57
Visible Light Photoredox Catalyzed Trifluoromethylation-Ring Expansion via Semipinacol Rearrangement….Pages 59-80
Transition Metal Free Visible Light-Mediated Synthesis of Polycyclic Indolizines….Pages 81-107
Synthesis and Characterizations of Novel Metal-Organic Frameworks (MOFs)….Pages 109-126
Experimental Section….Pages 127-253
Back Matter….Pages 255-258



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